A comparative study on the interaction between tin(II) porphyrin and selected group 8B metals for potential application as reduction catalysts

We study the interaction between tin(II) porphyrin (SnPor) with platinum and non-precious Group 8B metals (iron, cobalt and nickel) by density functional theory and discuss the electronic properties of the resulting products. We also model the interaction of the resulting compounds with water where applicable. Our studies indicate that, SnPor-Ni possesses electronic properties similar to SnPor-Pt, suggesting that it may possess similar photocatalytic properties for reduction reactions, such as converting water to hydrogen gas.     

具p-Laplacian算子型奇异边值问题的正解

考虑一类p-Laplacian算子型泛函微分方程的奇异边值问题,利用锥不动点定理,得到了其正解及多个正解存在的充分条件．     

具功能反应的三种群捕食者——食饵系统数学模型稳定性的研究

[1]中提出了具有功能反应的三种群捕食者——食饵系统的两种模型(Ⅰ)、(Ⅱ),并给出了局部渐近稳定的条件。本文研究了另外两种模型(Ⅲ)和(Ⅳ)的局部渐近稳定的条件。     

Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses

Er³⁺-doped tellurite glasses with molar compositions of xNb₂O₅-(14.7-x)Na₂O--10ZnO--5K₂O--10GeO₂-- 60TeO₂--0.3Er₂O₃ (x=0, 3, 5, 7 and 9) have been investigated for developing 1.5~μm fibre and planar amplifiers. The effects of Nb₂O₅ on the thermal stability and optical properties of Er³⁺-doped tellurite glasses have been discussed. It is noted that the incorporation of Nb₂O₅ (x=5) increases the thermal stability of tellurite glasses significantly. Er³⁺-doped niobium tellurite glasses exhibit a large stimulated emission cross-section (7.2\times 10^-21- 10.7×10^-21~cm² and the gain bandwidth, FWHM×\sigma_e^{\rm peak} (274\times 10^-28 - 480×10^-28~cm³), which are significantly higher than that of silicate and phosphate glasses. In addition, the intensity of upconversion luminescence of the Er³⁺-doped niobium tellurite glasses decreases rapidly with increasing Nb₂O₅ content. As a result, Er³⁺-doped niobium tellurite glasses might be a potential candidate for developing laser or optical amplifier devices.     

折射率连续周期分布一维光子晶体的带隙分析

微分传输矩阵法(DTMM)可以解析求解一维非均匀介质中的波动方程。用该方法,对几种折射率连续且周期分布的一维光子晶体进行了带隙分析。结果表明,折射率连续变化的一维周期结构也具有明显的带隙特征,折射率变化越平缓,光带隙的宽度越小。对于折射率正弦变化的一维光子晶体,其折射率变化得越剧烈,光子晶体的中心频率越小,带隙越宽;同时,折射率的平均值越大,中心频率越小,带隙越窄。由于材料的物理特性都是连续变化的,同样可以把结构推广到一维周期性功能梯度材料。     

动态柱形空穴膨胀模型及其在侵彻问题中的应用

 在侵彻问题中的应用进行了研究。通过采用相似变换求解塑性区控制方程，获得了动态柱形空穴膨胀中的弹塑性界面速度、径向应力分布、空穴表面应力的解。基于柱形空穴模型，推导了侵彻方程，并将其得到的预测结果与侵彻实验数据进行了比较。结果表明，模型的理论解与现有数据吻合得很好。 结果还显示了材料的可压缩性和塑性强化模量对柱形空穴膨胀以及侵彻阻力的影响。     

基于LiCo0.8M0.2O2 (M=Ni,Zr)薄膜的全固态薄膜锂电池

用射频磁控溅射结合传统退火的方法制备LiCo0.8M0.2O2 (M=Ni,Zr)阴极薄膜．X射线衍射、拉曼光谱、扫描电子显微镜等手段表征了不同掺杂的LiCo0.8M0.2O2薄膜．结果显示,700℃退火的LiCo0.8M0．2O2薄膜具有类似α-NaFeO2的层状结构．通过对不同掺杂锂钴氧阴极的全固态薄膜锂电池Li／LiPON／LiCo0.8M0.2O2的电化学性能研究表明,电化学活性元素Ni的掺杂使全固态电池具有更大的放电容量(56μAh／cm2μm),而非电化学活性元素Zr的掺杂使全固态电池具有更好的循环稳定性．     

Optical spectroscopy of Yb/Er codoped NaY(WO4)2 crystal

Erbium and ytterbium codoped double tungstates NaY(WO₄)₂ crystals were prepared by using Czochralski (CZ) pulling method. The absorption spectra in the region 290-2000 nm have been recorded at room temperature. The Judd-Ofelt theory was applied to the measured values of absorption line strengths to evaluate the spontaneous emission probabilities and stimulated emission cross sections of Er³⁺ ions in NaY(WO₄)₂ crystals. Intensive green and red lights were measured when the sample were pumped by a 974 nm laser diode (LD), especially, the intensities of green upconversion luminescence are very strong. The mechanism of energy transfer from Yb³⁺ to Er³⁺ ions was analyzed. Energy transfer and nonradiative relaxation played an important role in the upconversion process. Photoexcited luminescence experiments are also fulfilled to help analyzing the transit processes of the energy levels.     

两种蓝色有机电致发光材料

重点研究以两种蓝色OEL材料蒽类衍生物JBEM和联苯乙烯衍生物DPVBi分别作基质，以perylene作掺杂剂的器件的电致发光性能，特别研究了它稳定性，在这度和效率方面，两种器件并没有很大差别，然而在稳定性方面却有很大差别，蒽类衍生物JBEM的器件在100cd/m^2初始亮度下，半亮度寿命可达1035h，而DPVBi的器件在同样条件下，半亮度寿命为255h。通过分析两种器件的能级图，认为稳定性的差别可能源于两种蓝光材料本身的热稳定性不同，JBEM优于DPVBi，是一种很有前途的蓝色发光材料。